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- W2078290379 abstract "The lifetime of the first excited level of the symmetric C-H stretching mode of ${mathrm{CH}}_{3}$S chemisorbed on a Ag(111) surface was measured by picosecond vibrational spectroscopy. A biexponential decay (ensuremath{sim}3- and 63-ps lifetimes at 300 K) was observed, with a substantial temperature dependence of the slow component. Both decay processes are assigned to intramolecular vibrational relaxation. The decay rates are 2 orders of magnitude too fast to be explained by electron-hole-pair damping by the metal substrate." @default.
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- W2078290379 date "1990-04-23" @default.
- W2078290379 modified "2023-09-24" @default.
- W2078290379 title "Molecular vibrational energy relaxation at a metal surface: Methyl thiolate on Ag(111)" @default.
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- W2078290379 doi "https://doi.org/10.1103/physrevlett.64.2086" @default.
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