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- W2078294580 abstract "The electrical resistivity, the electronic and infrared spectra, and the crystal structure in bis(dimethylglyoximato)Pt(II), Pt(dmg)2, have been studied at high pressures. The electrical resistivity in the single crystal was measured under quasi-hydrostatic condition. The resistivity drastically decreased with increasing pressure; the metallic behavior was observed at around 4.6 GPa. Pt(dmg)2 behaved again as a semiconductor above about 6 GPa. A new absorption band was found above 6 GPa. The intensity of the absorption band was abruptly increased with pressure over a narrow pressure range of 6 to 8 Gpa. The crystal structure of the complex was studied at high pressures. X-ray work for a single crystal was carried out by the use of the diamond-anvil cell developed by Merrill and Bassett. The lattice constants of three axes decreased rapidly with pressure; the b lattice constant was not sensitive to pressure above 1.5 GPa. Strong intermolecular contacts of O—HC type was observed between adjacent chains along the b axis at high pressure. The relation between the structure and the electrical and optical properties at high pressure is discussed." @default.
- W2078294580 created "2016-06-24" @default.
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- W2078294580 date "1989-03-01" @default.
- W2078294580 modified "2023-10-17" @default.
- W2078294580 title "Electrical and optical properties and crystal structure of bis (dimethylglyoximato)Pt(II) at high pressures" @default.
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- W2078294580 doi "https://doi.org/10.1016/0379-6779(89)90889-8" @default.
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