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- W2078295587 abstract "The adsorption of 4-nitrophenol from aqueous solutions at activated FAS-1 charcoal was studied at 293, 308, 318, and 328 K. The experimental data obey the Dubinin-Astakhov-Stoeckli equation (a special case of the Dubinin-Radushkevich equation) for different exponents n. For experimental adsorption isotherms, the characteristic curve of the micropore volume filling theory was not temperature-invariant. However, these adsorption isotherms were described by the Dubinin-Radushkevich equation with n = 8 over a wide concentration range. This satisfactory description and the nonlinearity of the adsorption isotherms in the Dubinin-Astakhov-Stoeckli coordinates (for different n values) for low filling values are probably associated with competitive adsorption of water and 4-nitrophenol molecules in small micropores of the adsorbent. The calculated isosteric heats of adsorption increase with the adsorbed amount, which is also the case that the characteristic curve is not temperature-invariant." @default.
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- W2078295587 date "2008-07-01" @default.
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- W2078295587 title "Thermodynamics of the adsorption of 4-nitrophenol from aqueous solutions at activated charcoal" @default.
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- W2078295587 doi "https://doi.org/10.1134/s0033173208040048" @default.
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