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- W2078296845 abstract "One-electron oxidation of a stable tris[di-tert-butyl(methyl)silyl]silyl radical by the triphenylmethylium ion produces the corresponding silylium ion 2. However, this underwent a rapid intramolecular methyl group migration to form a more stable silylium ion 4 via a Wagner–Meerwein type rearrangement. The facile 1,3-methyl migration over the three peripheral silicon atoms in 4 was observed in NMR time scale." @default.
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- W2078296845 date "2004-01-01" @default.
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- W2078296845 title "Silylium Ion to Silylium Ion Rearrangement Caused by 1,3-Methyl Migration" @default.
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- W2078296845 doi "https://doi.org/10.1246/cl.2004.38" @default.
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