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- W2078307939 abstract "In the base-catalyzed polymerization of p-vinylbenzamide, hydrogen-transfer polymerization occurs. The structure of the new polymer was identified. Various effects on the hydrogen-transfer polymerization of p-vinylbenzamide were studied. The infrared spectrum of the oligomer has characteristic absorptions of secondary amide, as well as weak absorption of the vinyl group. The oligomer also gives a hydrogen-migrated polymer with anionic catalysts. From these facts a possible polymerization mechanism was proposed. The hydrogen-transfer polymerization occurred most readily with the p-vinylbenzamide, next and to a small extent with the meta-substituted isomer, and hardly with the o-substituted isomer. o-Vinylbenzamide gives 3,4-dihydroisocarbostyril." @default.
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- W2078307939 date "1967-11-01" @default.
- W2078307939 modified "2023-09-26" @default.
- W2078307939 title "Polymerization of vinylbenzamides" @default.
- W2078307939 doi "https://doi.org/10.1002/pol.1967.150051119" @default.
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