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- W2078309144 abstract "Triphenylgermane easily adds to acetylenes or terminal olefins in the presence of Et3B to give alkenyltriphenylgermane or alkyltriphenylgermane respectively under excellent control of regio- and stereoselectivities. While Et3B catalyzed addition of Ph3GeH to 1-dodecyne at −78 °C affords (Z)-1-triphenygermyl-1-dodecene exclusively, the addition of Ph3GeH at 60 °C provides (E)-1-triphenylgermyl-1-dodecene as a single product. The triphenylgermyl radical is also effective to isomerize Z-olefins into their thermodynamically more stable E-isomers." @default.
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- W2078309144 date "1990-08-01" @default.
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- W2078309144 title "Et<sub>3</sub>B Induced Stereoselective Radical Addition of Ph<sub>3</sub>GeH to Carbon–Carbon Multiple Bonds and Its Application to Isomerization of Olefins" @default.
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- W2078309144 doi "https://doi.org/10.1246/bcsj.63.2268" @default.
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