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- W2078314303 abstract "Abstract The absolute intensities of forbidden Δk = ±2 transitions to the ν4 vibrational state of 14NH3 have been derived from the Fourier transform spectra measured with the multipass White-type cell. Using expressions derived by the contact transformation method, the intensity data have been analyzed in order to obtain information on the mixing of vibration-rotation wavefunctions with different values of quantum numbers (k − lt). The parameter γ4 of the “2, −1” l-type operator, which is indeterminable from an anlaysis of transition frequencies because of correlations in the reduced Hamiltonian, has been determined to be 0.0563 (16) cm−1." @default.
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- W2078314303 date "1990-09-01" @default.
- W2078314303 modified "2023-10-06" @default.
- W2078314303 title "Interpretation of intensities of forbidden vibration-rotation transitions in Fourier transform spectra of ammonia" @default.
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- W2078314303 doi "https://doi.org/10.1016/0022-2852(90)90258-r" @default.
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