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- W2078318263 abstract "[formula: see text] The synthesis of all four diastereomers of bis(propionates), 3,5-dialkoxy-2,4-dimethylalkanals, by non-aldol aldol chemistry is described. The epoxy alcohols (3, 4) were converted into the mesylates (9, 11) which were cleanly rearranged to the desired 3,5-bis(oxygenated)-2,4-dimethylalkanals (10, 12) in high yield. The epoxy mesylates (13, 16) gave the desired products (14, 17) in good yield on treatment with TMSOTf and a hindered base." @default.
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- W2078318263 date "1999-06-11" @default.
- W2078318263 modified "2023-10-09" @default.
- W2078318263 title "Synthesis of Four Diastereomeric 3,5-Dialkoxy-2,4-dimethylalkanals by a Simple Extension of the Non-Aldol Aldol Process to Bis(propionates)" @default.
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- W2078318263 doi "https://doi.org/10.1021/ol990619+" @default.
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