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- W2078320481 abstract "Abstract Electrical and mechanical properties of elongated gold-molecule-gold junctions formed by tolane-type molecules with different anchoring groups (pyridyl, thiol, amine, nitrile and dihydrobenzothiophene) were studied in current-sensing force spectroscopy experiments and density functional simulations. Correlations between forces, conductances and junction geometries demonstrate that aromatic tolanes bind between electrodes as single molecules or as weakly-conductive dimers held by mechanically-weak π − π stacking. In contrast with the other anchors that form only S-Au or N-Au bonds, the pyridyl ring also forms a highly-conductive cofacial link to the gold surface. Binding of multiple molecules creates junctions with higher conductances and mechanical strengths than the single-molecule ones." @default.
- W2078320481 created "2016-06-24" @default.
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- W2078320481 date "2015-03-11" @default.
- W2078320481 modified "2023-10-15" @default.
- W2078320481 title "Correlation of breaking forces, conductances and geometries of molecular junctions" @default.
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- W2078320481 doi "https://doi.org/10.1038/srep09002" @default.
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