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• W2078322346 abstract "A three step synthesis of (R)-(−)-baclofen is described. The key step is the orthoester Claisen rearrangement of enantiopure allylic alcohol (S,E)-(−)-1a, affording γ,δ-unsaturated ester (S,E)-(+)-6 with high stereoselectivity. This latter derivative is converted into (R)-(−)-baclofen through a high yield one-pot reaction." @default.
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• W2078322346 date "1997-11-01" @default.
• W2078322346 modified "2023-10-03" @default.
• W2078322346 title "Enantioselective synthesis of β-substituted butyric acid derivatives via orthoester Claisen rearrangement of enzymatically resolved allylic alcohols: application to the synthesis of (R)-(−)-baclofen" @default.
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• W2078322346 doi "https://doi.org/10.1016/s0957-4166(97)00538-7" @default.
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