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- W2078329097 abstract "The 1N-(N,N-diethylaminoethyl)-2-arylazoaniline, HL [where HL = ArN = NC6H4N(H){C2H4N(C2H5)2}; Ar = C6H5 (for HL1), p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)], ligands were prepared by treating the appropriate 2-(arylazo)aniline with 2-bromo-N,N-diethylethanamine. Reactions of Na2PdCl4 with HL afforded the [(L)PdCl] complexes. HL binds palladium(II) in a tridentate fashion (N,N,N), forming a new diazoketiminato chelate. The X-ray structure of [(L3)PdCl] was determined to confirm the characterization. The newly synthesized complex [(L1)PdCl] was utilized to carry out Suzuki and Heck reactions for a variety of substrates." @default.
- W2078329097 created "2016-06-24" @default.
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- W2078329097 date "2012-02-01" @default.
- W2078329097 modified "2023-10-11" @default.
- W2078329097 title "Synthesis, characterization and structure of new diazoketiminato chelates of palladium(II): Potential catalyst for C–C coupling reactions" @default.
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- W2078329097 doi "https://doi.org/10.1016/j.poly.2011.11.026" @default.
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