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• W2078353000 startingPage "7278" @default.
• W2078353000 abstract "Reactions of nitrosobenzene and N,N‘-diethyl-4-nitrosoaniline with [Cu(CH3CN)4]PF6 produce novel homoleptic Cu(I)−nitrosoarene complexes, [Cu(ArNO)3]PF6, 1 (Ar = Ph) and 2 (Ar = 4-Et2NC6H4NO). The X-ray structure of 2 reveals that the copper is coordinated in a severely distorted trigonal planar geometry to the N-atom of the nitrosoarene ligand. Reactions of the PhNO complex 1 with olefins and an olefin/diene mixture provide evidence for its role as an intermediate and possibly the active nitrogen transfer agent in the Cu-catalyzed allylic amination of olefins by aryl hydroxylamines." @default.
• W2078353000 created "2016-06-24" @default.
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• W2078353000 date "2005-04-27" @default.
• W2078353000 modified "2023-10-17" @default.
• W2078353000 title "Nitrosoarene−Cu(I) Complexes Are Intermediates in Copper-Catalyzed Allylic Amination" @default.
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• W2078353000 doi "https://doi.org/10.1021/ja044093m" @default.
• W2078353000 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15898753" @default.
• W2078353000 hasPublicationYear "2005" @default.
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