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- W2078355416 abstract "Dynamic contact angles were measured by means of the technique of the capillary rise at a vertical plate. The solid surfaces were smooth as well as roughened glass microscope slides which were siliconized, the measuring liquid was doubly distilled water. On the smooth surfaces an initial increase of contact angle with increasing rate of advance of the three-phase line was followed by a plateau, i.e., a region where the contact angle was independent of the rate of motion of the three-phase line. At still higher rates, near 0.5 mm/min, the contact angle started to increase again. The transition between these different modes was very sharp in all cases. On roughened glass slides the plateau observed for the smooth surfaces was not present, and the contact angle increased monotonically with increasing rate of motion of the three-phase line. These findings support the notion that the contact angle in the region where it is rate independent is the thermodynamically significant Young contact angle. Conversely, the presence of such a plateau region may be taken as a criterion for operational smoothness of the solid surface. The experimental findings also imply that the static contact angle is not necessarily the best choice for thermodynamic interpretations." @default.
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- W2078355416 date "1983-07-01" @default.
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- W2078355416 title "Dynamic contact angles on smooth and rough surfaces" @default.
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- W2078355416 doi "https://doi.org/10.1016/0021-9797(83)90241-2" @default.
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