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• W2078358003 abstract "Hydrothermal treatments of 2-(pyridin-2-yl)acetonitrile, NaN3, and Zn(NO3)2 · 4H2O (or Cd(NO3)2 · 4H2O) in the presence of water and ethanol afford in situ tetrazole coordination polymers, C14H12N10Zn (1) and C14H12N10Cd (2). Both compounds are characterized by single crystal X-ray diffraction and display 2-D structures, while their 3-D packing views show different packing types (ABA sequence and AAA sequence). Crystal data of 1: Pbcn, a = 9.096(8), b = 8.681(7), c = 18.801(16) Å, α = β = γ = 90°, V = 1485(2) Å3, Z = 4, R 1 = 0.0315, wR 2 = 0.0883; Crystal data of 2: P21/c, a = 9.652(5), b = 10.024(3), c = 8.865(4) Å, β = 116.33(2)°, V = 768.7(6) Å3, Z = 2, R 1 = 0.0198, wR 2 = 0.0712. Both the compounds display similar fluorescence with emission peak at 390 nm, assigned to an intraligand fluorescent emission." @default.
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• W2078358003 date "2009-07-07" @default.
• W2078358003 modified "2023-09-25" @default.
• W2078358003 title "<i>In situ</i> syntheses of two tetrazole coordination polymers" @default.
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• W2078358003 doi "https://doi.org/10.1080/00958970902839410" @default.
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