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- W2078360973 abstract "The structure and properties of the oil-rich microemulsion (L2 phase) containing anionic polyelectrolyte, poly(acrylic acid) (PAA-H, Mw = 450 000) and its sodium salt PAA-Na (Mw = 30 000), were investigated. The cationic surfactant, didodecyldimethylammonium bromide (DDAB), which generates the rodlike aggregates in cyclohexane, was selected. Small-angle X-ray scattering, dynamic light scattering, electric conductivity, and viscosity measurements were performed. The rodlike structure was unchanged upon dissolving the polymers. PAA-Na is a strong polyelectrolyte, which takes a rather extended conformation in the bulk aqueous solution. However, PAA-Na adsorbed DDAB molecules by electrostatic interaction in the microemulsions. Then, the extended conformation was loosened in the microemulsion and was dissolved within the water pool of the DDAB aggregates. The characteristic size of the PAA-Na dissolved within the water pool of the DDAB aggregates was similar to that of the original DDAB aggregates. High-molecu..." @default.
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- W2078360973 date "1998-07-17" @default.
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- W2078360973 title "Structure and Properties of Fluids Composed of Polyelectrolyte and Ionic Surfactant in Organic Phase: Poly(acrylic acid) and Didodecyldimethylammonium Bromide" @default.
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- W2078360973 doi "https://doi.org/10.1021/la971283k" @default.
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