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- W2078361723 abstract "It was established that cleavage of 9,10-epoxiperfluorodecaline (I) under the action of MF (M = K, Cs) is a reversible reaction. Treatment of (I) with MF in polar aprotic solvents (glymes, DMF, DMSO) at 80-100°C resulted in quantitative formation of alcoholate (II) Heating (II) in diglyme with simultaneous distillation brings the reaction back to (I) with quantitative yield. If we heat (II) in tetraglyme at 180-200°C epoxide (III) is formed with high yield (74%). The formation of (I) and (III) proves a rare case of nucleophilic substitution of fluorine at sp3-hybridized carbon atom." @default.
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- W2078361723 date "1989-10-01" @default.
- W2078361723 modified "2023-09-23" @default.
- W2078361723 title "Intramolecular nucleophilic substitution of fluorine: Isomerisation of 9,10-epoxiperfluorodecaline into 1,9-epoxiperfluorodecaline" @default.
- W2078361723 doi "https://doi.org/10.1016/s0022-1139(00)84504-2" @default.
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