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- W2078363436 abstract "Abstract Oxidative ring opening reactions enabled disassembly of the cage structure of the title compound. Stepwise oxidations were achieved through radical intermediates using lead tetracetate and iodine. The regioselectivity of bond fission is rationalized by comparing the relative strains of each bond. Multiple cleavages of C‐C bond were accomplished by photolysis with HgO and iodine under UV. The oxidative effect of Ce(IV) ion on a cage‐shaped diketone is examined. New skeletons of polyquinanes are obtained from these reactions." @default.
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- W2078363436 date "1994-12-01" @default.
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- W2078363436 title "Chemistry of Cage-shaped Hydrocarbons. The Oxidation of Heptacyclo[6.6.0.0<sup>2,6</sup>.0<sup>3,13</sup>.0<sup>4,11</sup>.0<sup>5,9</sup>.0<sup>10,14</sup>]tetradecane" @default.
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- W2078363436 doi "https://doi.org/10.1002/jccs.199400116" @default.
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