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• W2078367279 endingPage "12029" @default.
• W2078367279 startingPage "12023" @default.
• W2078367279 abstract "The behavior of the phase transitions is mapped out as a function of the dihedral angle (ensuremath{theta}) or the transfer integral $(t)$ between donor columns for ensuremath{theta}-type BEDT-TTF [BEDT-TTF: bis(ethylenedithio)tetrathiafulvalene, abbreviated as ET] salts involving the series $ensuremath{theta}ensuremath{-}(mathrm{B}mathrm{E}mathrm{D}mathrm{T}ensuremath{-}mathrm{T}mathrm{T}mathrm{F}{)}_{2}{mathrm{MM}}^{ensuremath{'}}(mathrm{SCN}{)}_{4}$ [$M=mathrm{T}mathrm{l},mathrm{R}mathrm{b},mathrm{C}mathrm{s},$ ${M}^{ensuremath{'}}=mathrm{C}mathrm{o},mathrm{Z}mathrm{n}:$ abbreviated as $ensuremath{theta}{ensuremath{-}MM}^{ensuremath{'}}$], which we have recently prepared. The electronic correlation parameter $(U/t)$ increases by increasing the dihedral angle (ensuremath{theta}). In the phase diagram of ensuremath{theta}-ET salts the ground state varies from insulating, to superconducting, to metallic with decreasing ensuremath{theta}, namely, $U/t.$ The series $ensuremath{theta}{ensuremath{-}MM}^{ensuremath{'}}$ is located at the center of the phase diagram where metallic, paramagnetic insulating, and singlet states are observed at low temperatures. With applied pressure, the metal-insulator transition temperature rises because the dihedral angle increases, which is related to the enhancement of the electronic correlation." @default.
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• W2078367279 date "1998-05-15" @default.
• W2078367279 modified "2023-10-16" @default.
• W2078367279 title "Systematic study of the electronic state in θ-type BEDT-TTF organic conductors by changing the electronic correlation" @default.
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• W2078367279 doi "https://doi.org/10.1103/physrevb.57.12023" @default.
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