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- W2078375435 abstract "Up to now, little effort has been made to exploit large-area high-throughput patterning by block copolymer (BCP) lithography to generate nanostructured substrates with periods well below 100 nm for surface-enhanced Raman scattering (SERS). We show that simple BCP-templated galvanic displacement reactions yield dense arrays of mushroom-shaped gold nanopillars with a period of 50 nm. The nanoporous BCP films used as templates were obtained by swelling-induced reconstruction of reverse micelle monolayers deposited on silicon wafers. Coupling of adjacent mushroom caps almost impinging on each other combined with their strong local curvature results in a high spatial density of hot spots in the narrow gaps between them. Thus, substrates characterized by high SERS efficiencies are obtained." @default.
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- W2078375435 date "2009-05-21" @default.
- W2078375435 modified "2023-10-09" @default.
- W2078375435 title "Nanostructured Gold Films for SERS by Block Copolymer-Templated Galvanic Displacement Reactions" @default.
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- W2078375435 doi "https://doi.org/10.1021/nl900939y" @default.
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