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- W2078392471 abstract "Bifunctional periodic mesoporous organosilicas (PMOs) with —CH2—CH2—/—CH═CH— bridges have been synthesized using a salt assisted nonionic templating method. The ability to direct locations of the individual organic groups using a novel silica precursor prehydrolysis step is demonstrated. Depending on the prehydrolysis conditions the products showed either structural heterogeneities consisting of domains of the same functionality or a structurally homogeneous system, confirmed by 1H−29Si heteronuclear correlation (HETCOR) experiments. The resulting PMOs show large pore volumes (up to 1.34 cm3 g−1) and high surface areas (up to 1310 m2 g−1). The ability to form domain structures within the same mesostructure may have potential applications in molecular recognition and separation." @default.
- W2078392471 created "2016-06-24" @default.
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- W2078392471 date "2008-04-29" @default.
- W2078392471 modified "2023-10-14" @default.
- W2078392471 title "Periodic Mesoporous Organosilicas with Domain Functionality: Synthesis and Advanced Characterization" @default.
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- W2078392471 doi "https://doi.org/10.1021/cm7036124" @default.
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