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- W2078394469 abstract "An orthorhombic polymorph of titanium oxide (Ti(2)O(3)) has been synthesized at high pressure-high temperature (HP-HT) conditions. It has been refined in the Pnma space group and the Th(2)S(3) structural type with the unit cell parameters as follows: a = 7.8248(6) Å, b = 2.8507(4) Å, c = 8.0967(3) Å, V = 180.61(1) Å(3) and Z = 4. The samples of Pnma-Ti(2)O(3) were of a golden colour, in contrast to the conventional black corundum-structured Ti(2)O(3). The structural stability of this polymorph has been examined by simultaneous Raman and x-ray diffraction studies under high pressure over 70 GPa and high temperature over 2200 K. No phase transformations or chemical reactions have been established. The electrical resistivity of Th(2)S(3)-structured Ti(2)O(3) samples showed a semiconducting behaviour and, at ambient conditions, was equal to 0.20-0.46 Ω cm. Conventional near-infrared absorption spectroscopy established the absence of energy gaps above 0.25 eV." @default.
- W2078394469 created "2016-06-24" @default.
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- W2078394469 date "2010-08-31" @default.
- W2078394469 modified "2023-09-25" @default.
- W2078394469 title "Structural stability of a golden semiconducting orthorhombic polymorph of Ti<sub>2</sub>O<sub>3</sub>under high pressures and high temperatures" @default.
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- W2078394469 doi "https://doi.org/10.1088/0953-8984/22/37/375402" @default.
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