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- W2078394630 abstract "Charge disproportionation in La0.5Ca0.5FeO3-delta perovskite has been detected by zero-field Mossbauer spectra from 20 K to room temperature. On the basis of the parameters of center shifts and hyperfine fields, Mossbauer spectra identified that the iron ionic states are Fe3+ and Fe5+ below 150 K, Fe3+, Fe4+ and Fe5+ in the intermediate temperature region, as well as Fe3+ and Fe4+ above 220 K. At low temperatures, the system exhibits a cluster-glass-like state resulting from competition between antiferromagnetic interaction of Fe3+ -Fe3+ and ferromagnetic interaction of Fe3+-Fe5+. (C) 2006 Elsevier B.V. All rights reserved." @default.
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- W2078394630 date "2006-11-01" @default.
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- W2078394630 title "Mössbauer spectroscopy as a probe of magnetic states in La0.5Ca0.5FeO3−δ perovskite" @default.
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- W2078394630 doi "https://doi.org/10.1016/j.jmmm.2006.02.102" @default.
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