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• W2078395711 abstract "Abstract The synthesis, characterization and speciation of the VO 2+ –quinic acid system is described. Three new solid complexes were obtained: [VO(quin)(H 2 O) 3 ] ( I ), Na 4 [VO(quin) 2 SO 4 ]·4H 2 O ( II ) and Na 6 [VO(quin) 2 SO 4 ]·4H 2 O ( III ), at pH 3.5, 6 and 12, respectively. They were characterized by elemental analysis, diffuse reflectance, FTIR and Raman spectroscopies, and thermal behavior. Their stability constants were determined at 298 K and at a constant ionic strength of 0.150 M using potentiometric methods. In aqueous solution three different complexes appeared as the main species at the pH values indicated above as shown in the species distribution curves. Up to pH 8 the system behaves as a 2-hydroxyacid/metal-like compound, while at higher pH further deprotonations were observed, which resulted in the formation of sugar–VO 2+ -like complexes. UV–Vis spectra were also reported." @default.
• W2078395711 created "2016-06-24" @default.
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• W2078395711 date "2000-12-01" @default.
• W2078395711 modified "2023-09-24" @default.
• W2078395711 title "Oxovanadium(IV) complexes of quinic acid. Synthesis, characterization and potentiometric study" @default.
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• W2078395711 doi "https://doi.org/10.1016/s0277-5387(00)00567-2" @default.
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