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- W2078395973 abstract "Abstract Some new 2,6-bis(diphenylphosphinomethyl)pyridine (pnp) complexes of nickel(II), cobalt(II) and iron(II) were prepared and their physical properties were determined and compared with those of some previously described nickel(II) complexes. A pentaco-ordinate molecular structure (distorted tirgonal bipyramidal), instead of the previous square-planar, is now suggested for [Ni(pnp)2]2+. For Ni(pnp)-(NCS)2, previously described as a mixture of low-spin and high-spin forms of a five-co-ordinated molecule, the interallogon formulation [Ni(pnp)NCS] [Ni(pnp)-(NCS)3], which receives strong support from the experimental data, is suggested. The hexa-co-ordinated Ni(pnp)(NO3)2, the penta-co-ordinated high spin Co(pnp)(NO3)2 and Fe(pnp)(NO3)2, and the hexaco-ordinated low-spin [Co(pnp)2](ClO4)2 and [Fe(pnp)2](ClO4)2 are also described. The equilibrium constant for the hydration reaction of Ni(pnp)Cl2 in n-BuOHH2O solution is determined." @default.
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- W2078395973 date "1982-01-01" @default.
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- W2078395973 title "2,6-Bis(diphenylphosphinomethyl)pyridine complexes of nickel(II), cobalt(II), iron(II)" @default.
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- W2078395973 doi "https://doi.org/10.1016/s0020-1693(00)89120-3" @default.
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