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• W2078401995 abstract "Precipitons are molecular phase tags for chemical separations. They can be switched from a high-solubility to a low-solubility state to facilitate product, reagent, or catalyst isolation. This paper presents the first photoactivated precipiton and demonstrates that this precipiton is an efficient amine scavenging agent in solution-phase syntheses of amides, ureas, and imines. This approach to amine scavenging offers advantages over solid-phase scavenging methods. The amine is captured in a homogeneous medium, so the capture is much faster than seen with isocyanate resins, and only a small excess of the scavenger is required." @default.
• W2078401995 created "2016-06-24" @default.
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• W2078401995 date "2002-03-27" @default.
• W2078401995 modified "2023-10-16" @default.
• W2078401995 title "A Photoactivated Precipiton for Reagent Sequestration in Solution-Phase Synthesis" @default.
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• W2078401995 doi "https://doi.org/10.1021/ja017577g" @default.
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