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- W2078403487 abstract "Much attention has been paid to heterocyclic N-containing ligands due to their applicability as bridging ligands in the synthesis of redox active dinuclear metal complexes. With this aim, we report the synthesis and full characterization of a novel phthalazine-triazole ligand (1,4-bis(1-methyl-1H-1,2,3-triazol-4-yl)phthalazine). Moreover, we show that the phthalazine nitrogen atoms of this N-heterocyclic ligand are more reactive towards alkylating agents than the triazole groups. New ruthenium(II) complexes containing this ligand have been obtained and characterized both structurally and electrochemically. The geometry imposed by the ligand allows the placement of two ruthenium centers in very close proximity so that efficient through-space interactions take place, a concept of crucial importance for electron transfer processes." @default.
- W2078403487 created "2016-06-24" @default.
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- W2078403487 date "2014-01-01" @default.
- W2078403487 modified "2023-10-07" @default.
- W2078403487 title "Dinuclear ruthenium complexes containing a new ditopic phthalazin-bis(triazole) ligand that promotes metal–metal interactions" @default.
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- W2078403487 doi "https://doi.org/10.1039/c3nj01209c" @default.
- W2078403487 hasPublicationYear "2014" @default.
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