Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078415999> ?p ?o ?g. }
- W2078415999 endingPage "2208" @default.
- W2078415999 startingPage "2200" @default.
- W2078415999 abstract "Controlled/“living” radical polymerization (CLRP) of vinyl chloride (VC) via the reversible addition–fragmentation chain transfer (RAFT) process is reported for the first time. The cyanomethyl methyl(phenyl)carbamodithioate (CMPCD) was found to be an efficient RAFT agent enabling the CLRP polymerization of VC monomer under certain experimental conditions. Two different radical initiators, having very distinct half-life times at room temperature, were employed in this study. The kinetic studies of RAFT polymerization of VC show a linear increase of the molecular weight with the monomer conversion and the lowest polydispersity (PDI) ever reported for poly(vinyl chloride) (PVC) synthesized with CLRP method (PDI ∼ 1.4). The resulting PVC was fully characterized using the matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS), 1H nuclear magnetic resonance spectroscopy (1H NMR), and gel permeation chromatography (GPC) techniques. The 1H NMR and MALDI-TOF-MS analysis of PVC prepared via RAFT polymerization method have shown the absence of structural defects and the presence of chain-end functional groups. The “livingness” of the PVC was also confirmed by a successful reinitiation experiment. The suitability of the RAFT agent was also confirmed via high-level ab initio molecular orbital calculations." @default.
- W2078415999 created "2016-06-24" @default.
- W2078415999 creator A5006121678 @default.
- W2078415999 creator A5008450457 @default.
- W2078415999 creator A5013963430 @default.
- W2078415999 creator A5028464688 @default.
- W2078415999 creator A5074046086 @default.
- W2078415999 creator A5083158068 @default.
- W2078415999 creator A5084230544 @default.
- W2078415999 creator A5090298673 @default.
- W2078415999 date "2012-02-23" @default.
- W2078415999 modified "2023-10-11" @default.
- W2078415999 title "Reversible Addition–Fragmentation Chain Transfer Polymerization of Vinyl Chloride" @default.
- W2078415999 cites W1964845930 @default.
- W2078415999 cites W1966978757 @default.
- W2078415999 cites W1972295548 @default.
- W2078415999 cites W1974992989 @default.
- W2078415999 cites W1977308241 @default.
- W2078415999 cites W1982915834 @default.
- W2078415999 cites W1983134411 @default.
- W2078415999 cites W1990446411 @default.
- W2078415999 cites W1991901809 @default.
- W2078415999 cites W1995471167 @default.
- W2078415999 cites W1996473395 @default.
- W2078415999 cites W1997151511 @default.
- W2078415999 cites W2015663029 @default.
- W2078415999 cites W2030301734 @default.
- W2078415999 cites W2043924688 @default.
- W2078415999 cites W2055101178 @default.
- W2078415999 cites W2062643373 @default.
- W2078415999 cites W2065017422 @default.
- W2078415999 cites W2074554162 @default.
- W2078415999 cites W2075343842 @default.
- W2078415999 cites W2078089360 @default.
- W2078415999 cites W2078949209 @default.
- W2078415999 cites W2081361953 @default.
- W2078415999 cites W2088490639 @default.
- W2078415999 cites W2089042076 @default.
- W2078415999 cites W2090002194 @default.
- W2078415999 cites W2094941447 @default.
- W2078415999 cites W2113121540 @default.
- W2078415999 cites W2113390781 @default.
- W2078415999 cites W2116231389 @default.
- W2078415999 cites W2130166351 @default.
- W2078415999 cites W2131801486 @default.
- W2078415999 cites W2139414379 @default.
- W2078415999 cites W2150184000 @default.
- W2078415999 cites W2156795937 @default.
- W2078415999 cites W2159290712 @default.
- W2078415999 cites W2166880877 @default.
- W2078415999 cites W2168881742 @default.
- W2078415999 cites W2221957912 @default.
- W2078415999 cites W3104541550 @default.
- W2078415999 cites W4210975880 @default.
- W2078415999 doi "https://doi.org/10.1021/ma300064j" @default.
- W2078415999 hasPublicationYear "2012" @default.
- W2078415999 type Work @default.
- W2078415999 sameAs 2078415999 @default.
- W2078415999 citedByCount "61" @default.
- W2078415999 countsByYear W20784159992012 @default.
- W2078415999 countsByYear W20784159992013 @default.
- W2078415999 countsByYear W20784159992014 @default.
- W2078415999 countsByYear W20784159992015 @default.
- W2078415999 countsByYear W20784159992016 @default.
- W2078415999 countsByYear W20784159992017 @default.
- W2078415999 countsByYear W20784159992018 @default.
- W2078415999 countsByYear W20784159992019 @default.
- W2078415999 countsByYear W20784159992020 @default.
- W2078415999 countsByYear W20784159992021 @default.
- W2078415999 countsByYear W20784159992022 @default.
- W2078415999 countsByYear W20784159992023 @default.
- W2078415999 crossrefType "journal-article" @default.
- W2078415999 hasAuthorship W2078415999A5006121678 @default.
- W2078415999 hasAuthorship W2078415999A5008450457 @default.
- W2078415999 hasAuthorship W2078415999A5013963430 @default.
- W2078415999 hasAuthorship W2078415999A5028464688 @default.
- W2078415999 hasAuthorship W2078415999A5074046086 @default.
- W2078415999 hasAuthorship W2078415999A5083158068 @default.
- W2078415999 hasAuthorship W2078415999A5084230544 @default.
- W2078415999 hasAuthorship W2078415999A5090298673 @default.
- W2078415999 hasConcept C111998727 @default.
- W2078415999 hasConcept C11432220 @default.
- W2078415999 hasConcept C121120078 @default.
- W2078415999 hasConcept C158117686 @default.
- W2078415999 hasConcept C15920480 @default.
- W2078415999 hasConcept C166940927 @default.
- W2078415999 hasConcept C178790620 @default.
- W2078415999 hasConcept C185592680 @default.
- W2078415999 hasConcept C188027245 @default.
- W2078415999 hasConcept C2781460079 @default.
- W2078415999 hasConcept C34594497 @default.
- W2078415999 hasConcept C44228677 @default.
- W2078415999 hasConcept C48396125 @default.
- W2078415999 hasConcept C521977710 @default.
- W2078415999 hasConcept C63179538 @default.
- W2078415999 hasConcept C9132879 @default.
- W2078415999 hasConceptScore W2078415999C111998727 @default.
- W2078415999 hasConceptScore W2078415999C11432220 @default.