Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078416596> ?p ?o ?g. }
- W2078416596 endingPage "1753" @default.
- W2078416596 startingPage "1739" @default.
- W2078416596 abstract "Reversible addition fragmentation transfer (RAFT) copolymerization with benzyl dithiobenzoate (BDTB) as chain transfer agent was used to copolymerize maleic anhydride (MA) with styrene (St) and with the substituted styrenes p-chlorostyrene (pClSt), p-methoxystyrene (pMeOSt) and p-methylstyrene (pMeSt). Kinetic studies indicated that radical copolymerizations proceeded with apparent ‘living’ character, deduced from experiments demonstrating an increase in molar mass with monomer conversion, narrow molar mass distribution and chain extension to form block copolymer. All copolymers were alternating in chain structure as confirmed by determinations of monomer reactivity ratios. The degree of control in the RAFT mechanism and the establishment of the fragmentation equilibrium incorporating MA are discussed for styrene and for p-substituted styrenes, in relation to experimental copolymerizations producing molar masses somewhat higher than expected. For copolymerizations of MA with α-methylstyrene (αMeSt), conventional rather than controlled behaviour was observed, suggesting that the fragmentation equilibrium could be shifted towards the αMeSt propagating radical." @default.
- W2078416596 created "2016-06-24" @default.
- W2078416596 creator A5004561977 @default.
- W2078416596 creator A5008788351 @default.
- W2078416596 creator A5071985939 @default.
- W2078416596 date "2005-02-01" @default.
- W2078416596 modified "2023-10-17" @default.
- W2078416596 title "Radical copolymerization of maleic anhydride and substituted styrenes by reversible addition-fragmentation chain transfer (RAFT) polymerization" @default.
- W2078416596 cites W1964918647 @default.
- W2078416596 cites W1975434999 @default.
- W2078416596 cites W2003033997 @default.
- W2078416596 cites W2021129620 @default.
- W2078416596 cites W2025232569 @default.
- W2078416596 cites W2027761597 @default.
- W2078416596 cites W2032884764 @default.
- W2078416596 cites W2036062366 @default.
- W2078416596 cites W2036148675 @default.
- W2078416596 cites W2036333105 @default.
- W2078416596 cites W2040582832 @default.
- W2078416596 cites W2045055557 @default.
- W2078416596 cites W2048091284 @default.
- W2078416596 cites W2048178264 @default.
- W2078416596 cites W2055393399 @default.
- W2078416596 cites W2061845232 @default.
- W2078416596 cites W2062074106 @default.
- W2078416596 cites W2062852684 @default.
- W2078416596 cites W2064293382 @default.
- W2078416596 cites W2074554162 @default.
- W2078416596 cites W2077844474 @default.
- W2078416596 cites W2081110196 @default.
- W2078416596 cites W2081361953 @default.
- W2078416596 cites W2082138855 @default.
- W2078416596 cites W2094329519 @default.
- W2078416596 cites W2097313251 @default.
- W2078416596 cites W2117705782 @default.
- W2078416596 cites W2135649714 @default.
- W2078416596 cites W2139414379 @default.
- W2078416596 cites W2139932144 @default.
- W2078416596 cites W2150184000 @default.
- W2078416596 cites W2159719930 @default.
- W2078416596 cites W2164821551 @default.
- W2078416596 cites W2166155968 @default.
- W2078416596 cites W2171522089 @default.
- W2078416596 cites W2489001055 @default.
- W2078416596 doi "https://doi.org/10.1016/j.polymer.2004.12.037" @default.
- W2078416596 hasPublicationYear "2005" @default.
- W2078416596 type Work @default.
- W2078416596 sameAs 2078416596 @default.
- W2078416596 citedByCount "75" @default.
- W2078416596 countsByYear W20784165962012 @default.
- W2078416596 countsByYear W20784165962013 @default.
- W2078416596 countsByYear W20784165962014 @default.
- W2078416596 countsByYear W20784165962015 @default.
- W2078416596 countsByYear W20784165962016 @default.
- W2078416596 countsByYear W20784165962017 @default.
- W2078416596 countsByYear W20784165962018 @default.
- W2078416596 countsByYear W20784165962019 @default.
- W2078416596 countsByYear W20784165962020 @default.
- W2078416596 countsByYear W20784165962021 @default.
- W2078416596 countsByYear W20784165962023 @default.
- W2078416596 crossrefType "journal-article" @default.
- W2078416596 hasAuthorship W2078416596A5004561977 @default.
- W2078416596 hasAuthorship W2078416596A5008788351 @default.
- W2078416596 hasAuthorship W2078416596A5071985939 @default.
- W2078416596 hasConcept C111919701 @default.
- W2078416596 hasConcept C111998727 @default.
- W2078416596 hasConcept C121120078 @default.
- W2078416596 hasConcept C142724271 @default.
- W2078416596 hasConcept C158117686 @default.
- W2078416596 hasConcept C15920480 @default.
- W2078416596 hasConcept C166940927 @default.
- W2078416596 hasConcept C178790620 @default.
- W2078416596 hasConcept C185592680 @default.
- W2078416596 hasConcept C188027245 @default.
- W2078416596 hasConcept C191015642 @default.
- W2078416596 hasConcept C196503311 @default.
- W2078416596 hasConcept C204787440 @default.
- W2078416596 hasConcept C2776910235 @default.
- W2078416596 hasConcept C2777566558 @default.
- W2078416596 hasConcept C2777666793 @default.
- W2078416596 hasConcept C2779353670 @default.
- W2078416596 hasConcept C34594497 @default.
- W2078416596 hasConcept C41008148 @default.
- W2078416596 hasConcept C44228677 @default.
- W2078416596 hasConcept C48396125 @default.
- W2078416596 hasConcept C521977710 @default.
- W2078416596 hasConcept C71924100 @default.
- W2078416596 hasConcept C9132879 @default.
- W2078416596 hasConceptScore W2078416596C111919701 @default.
- W2078416596 hasConceptScore W2078416596C111998727 @default.
- W2078416596 hasConceptScore W2078416596C121120078 @default.
- W2078416596 hasConceptScore W2078416596C142724271 @default.
- W2078416596 hasConceptScore W2078416596C158117686 @default.
- W2078416596 hasConceptScore W2078416596C15920480 @default.
- W2078416596 hasConceptScore W2078416596C166940927 @default.
- W2078416596 hasConceptScore W2078416596C178790620 @default.
- W2078416596 hasConceptScore W2078416596C185592680 @default.
- W2078416596 hasConceptScore W2078416596C188027245 @default.