FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078422585> ?p ?o ?g. }

• W2078422585 abstract "Abstract The compounds (CO) 5 CrEPhH 2 (E  P, II ; E  As, VIII ) react with RP(CCH) 2 (R  t Bu, Ia ; R  CH 2 Ph, Ib ) and Me 2 Sn(CCPh)2 ( V ) via insertion into the EH bonds to give 1,4-dihetero-cyclohexa-2,5-diene complexes of the type [(CO) 5 Cr](Ph) PCHCHXCHC H (X  RP, III ; X  PhAs, IX ) and [(CO) 5 Cr](Ph)PC(Ph)CHSnMe 2 CHC (Ph) ( VII ) in high yields. The insertion of the dialkynes is stereospecific: trans addition of II to V yields first [(CO) 5 Cr](Ph)(H)PC(Ph)CHSnMe 2 C CPh ( VI ) a compound in which the phosphorus group and the Me 2 Sn(CCPh) unit are in cis position to each other. Ring closure by insertion of the second phenylethynyl group in VI into the PH bond affords the six membered cycle of [(CO) 5 Cr](Ph) P  C(Ph)CHSnMe 2 CHC (Ph) ( VII ). Another way to synthesize complexes of the type VII is given in the reaction of I with H 2 Sn n Bu 2 ( XIII ). In the presence of KOH/18-Crown-6, the cycles of R PCHCHSn n Bu 2 CHC H (R  t Bu, XIVa ; R  CH 2 Ph, XIVb ) are formed, which then yields by treatment with (CO) 5 Cr(Thf) ( XV ), [(CO) 5 Cr](R) PCHCHSn n Bu 2 CHC H (R  t Bu, XVIa ; R  CH 2 Ph, XVIb ). A compound, in which both hetero-atoms of the 1-phospha-4-arsacyclohexa-2,5-diene ( IXa ) are bonded to a 16-electron complex fragment can be synthesized by the reaction of IXa with (CO) 5 Mo(Thf) ( X ). [(CO) 5 Cr]( t Bu) P CHCHAs(Ph)[Mo(CO) 5 ]CHC H ( XII ) can be isolated in high yields. The identity of all new synthesized compounds III, VI, VII, IX, XII, XIV and XVI is confirmed by analytical and spectroscopic (IR, MS, 1 H, 13 C and 31 P NMR) data as well as by an X-ray diffraction study of IXa ." @default.
• W2078422585 created "2016-06-24" @default.
• W2078422585 creator A5039877065 @default.
• W2078422585 creator A5061298275 @default.
• W2078422585 creator A5089437875 @default.
• W2078422585 date "1993-02-01" @default.
• W2078422585 modified "2023-09-27" @default.
• W2078422585 title "Additionsreaktionen von (CO)5CrEPhH2(E  P As) an di(ethinyl)-phosphane und stannane; stufenweise darstellung von komplex-gebundenen 1,4-dihetero-cyclohexa-2,5-dienen" @default.
• W2078422585 cites W1503885849 @default.
• W2078422585 cites W2008218421 @default.
• W2078422585 cites W2021295685 @default.
• W2078422585 cites W2025884413 @default.
• W2078422585 cites W2044477622 @default.
• W2078422585 cites W2045517215 @default.
• W2078422585 cites W2046462975 @default.
• W2078422585 cites W2048341950 @default.
• W2078422585 cites W2066779501 @default.
• W2078422585 cites W2160693355 @default.
• W2078422585 doi "https://doi.org/10.1016/0022-328x(93)83054-y" @default.
• W2078422585 hasPublicationYear "1993" @default.
• W2078422585 type Work @default.
• W2078422585 sameAs 2078422585 @default.
• W2078422585 citedByCount "11" @default.
• W2078422585 countsByYear W20784225852019 @default.
• W2078422585 crossrefType "journal-article" @default.
• W2078422585 hasAuthorship W2078422585A5039877065 @default.
• W2078422585 hasAuthorship W2078422585A5061298275 @default.
• W2078422585 hasAuthorship W2078422585A5089437875 @default.
• W2078422585 hasConcept C155647269 @default.
• W2078422585 hasConcept C185592680 @default.
• W2078422585 hasConcept C71240020 @default.
• W2078422585 hasConceptScore W2078422585C155647269 @default.
• W2078422585 hasConceptScore W2078422585C185592680 @default.
• W2078422585 hasConceptScore W2078422585C71240020 @default.
• W2078422585 hasLocation W20784225851 @default.
• W2078422585 hasOpenAccess W2078422585 @default.
• W2078422585 hasPrimaryLocation W20784225851 @default.
• W2078422585 isParatext "false" @default.
• W2078422585 isRetracted "false" @default.
• W2078422585 magId "2078422585" @default.
• W2078422585 workType "article" @default.