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- W2078426089 abstract "Photodissociation of Cr(CO)6 induced by a KrF* excimer laser (248 nm) was examined under molecular beam conditions, using a quadrupole mass spectrometer with electron impact ionization (11–19 eV) to detect the products as their respective ions. The ions of all Cr(CO)x products (x=0–5) were produced upon photodissociation of Cr(CO)6 at laser fluences from 1 to 10 mJ cm−2. The quantitative behavior of the Cr(CO)+x product ion yields vs laser fluence as well as statistical rate calculations indicate that Cr(CO)4 is the major product formed upon single-photon dissociation of Cr(CO)6 under collisionless conditions at 248 nm. The additional Cr(CO)+x (x<4) product ions observed at low fluences are formed primarily by electron-impact fragmentation of Cr(CO)4 in the mass spectrometer ionizer. At laser fluences ≳5 mJ cm−2, secondary photodissociation of Cr(CO)4 becomes important. Cr(CO)2 is assigned as the major photoproduct formed via secondary photodissociation of Cr(CO)4." @default.
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- W2078426089 date "1989-09-01" @default.
- W2078426089 modified "2023-10-16" @default.
- W2078426089 title "Photodissociation of Cr(CO)6 in a molecular beam at 248 nm: Observation of primary and secondary photoproducts by mass spectrometry" @default.
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- W2078426089 doi "https://doi.org/10.1063/1.456958" @default.
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