FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078441609> ?p ?o ?g. }

• W2078441609 endingPage "200" @default.
• W2078441609 startingPage "185" @default.
• W2078441609 abstract "A series of Ni aggregates supported on α-Al2O3 at different nickel contents are prepared by ionic exchange of Ni2+ followed by γ-irradiation under inert atmosphere. Characterization techniques are used at each step to select the elaboration conditions optimized for their use as catalysts. X-ray diffraction demonstrates the presence, after the Ni2+ adsorption step, of the phases (NiO)2(Al2O3)9 and (NiO)(Al2O3)16 that are favourable to further performances of the catalyst. After radiolysis, the phases of the oxide NiO and the metal Ni are observed. The relative amount of the Ni metal phase increases with the initial Ni2+ content. The nickel clusters (prepared from the complex [Ni(NH3)6]2+), imaged by Scanning Electron Microscope (SEM)/EDS, are highly dispersed. The H2 adsorption and thermodesorption study by chemisorption and H2-TPD indicates that the sites of the catalyst are occupied by hydrogen generated during irradiation. After H2 treatment at 350 °C, it shows high hydrogen adsorption/desorption capacity. When tested in the steam-reforming methane reaction (CH4+H2O→CO+3H2), the radiolytic Ni/α-Al2O3 samples exhibit quite promising catalytic properties, namely a high activity and a remarkably high selectivity in CO even at moderate temperature (80% at 550 °C with a conversion of 60%)." @default.
• W2078441609 created "2016-06-24" @default.
• W2078441609 creator A5005862133 @default.
• W2078441609 creator A5021066350 @default.
• W2078441609 creator A5028915027 @default.
• W2078441609 creator A5035138868 @default.
• W2078441609 creator A5036005842 @default.
• W2078441609 creator A5087925346 @default.
• W2078441609 date "2005-10-01" @default.
• W2078441609 modified "2023-10-17" @default.
• W2078441609 title "Radiation-induced synthesis of α-Al2O3 supported nickel clusters: Characterization and catalytic properties" @default.
• W2078441609 cites W1552243831 @default.
• W2078441609 cites W1648426565 @default.
• W2078441609 cites W1966441009 @default.
• W2078441609 cites W1967403817 @default.
• W2078441609 cites W1974069785 @default.
• W2078441609 cites W1979802922 @default.
• W2078441609 cites W1987040073 @default.
• W2078441609 cites W1990936716 @default.
• W2078441609 cites W1992170888 @default.
• W2078441609 cites W2000591009 @default.
• W2078441609 cites W2002729469 @default.
• W2078441609 cites W2009600186 @default.
• W2078441609 cites W2010125674 @default.
• W2078441609 cites W2011277131 @default.
• W2078441609 cites W2011411260 @default.
• W2078441609 cites W2022431590 @default.
• W2078441609 cites W2030997360 @default.
• W2078441609 cites W2034281777 @default.
• W2078441609 cites W2035202752 @default.
• W2078441609 cites W2050485732 @default.
• W2078441609 cites W2055113583 @default.
• W2078441609 cites W2071670762 @default.
• W2078441609 cites W2075830129 @default.
• W2078441609 cites W2082468040 @default.
• W2078441609 cites W2091698016 @default.
• W2078441609 cites W2092868971 @default.
• W2078441609 cites W2094817259 @default.
• W2078441609 cites W2102663755 @default.
• W2078441609 cites W2158636624 @default.
• W2078441609 cites W2195749374 @default.
• W2078441609 cites W2314418509 @default.
• W2078441609 cites W2478427702 @default.
• W2078441609 cites W2518815596 @default.
• W2078441609 cites W4244311792 @default.
• W2078441609 cites W4299446907 @default.
• W2078441609 cites W4376043836 @default.
• W2078441609 doi "https://doi.org/10.1016/j.radphyschem.2005.04.021" @default.
• W2078441609 hasPublicationYear "2005" @default.
• W2078441609 type Work @default.
• W2078441609 sameAs 2078441609 @default.
• W2078441609 citedByCount "35" @default.
• W2078441609 countsByYear W20784416092012 @default.
• W2078441609 countsByYear W20784416092013 @default.
• W2078441609 countsByYear W20784416092014 @default.
• W2078441609 countsByYear W20784416092017 @default.
• W2078441609 countsByYear W20784416092019 @default.
• W2078441609 countsByYear W20784416092020 @default.
• W2078441609 countsByYear W20784416092021 @default.
• W2078441609 countsByYear W20784416092022 @default.
• W2078441609 countsByYear W20784416092023 @default.
• W2078441609 crossrefType "journal-article" @default.
• W2078441609 hasAuthorship W2078441609A5005862133 @default.
• W2078441609 hasAuthorship W2078441609A5021066350 @default.
• W2078441609 hasAuthorship W2078441609A5028915027 @default.
• W2078441609 hasAuthorship W2078441609A5035138868 @default.
• W2078441609 hasAuthorship W2078441609A5036005842 @default.
• W2078441609 hasAuthorship W2078441609A5087925346 @default.
• W2078441609 hasConcept C147789679 @default.
• W2078441609 hasConcept C150394285 @default.
• W2078441609 hasConcept C161790260 @default.
• W2078441609 hasConcept C162711632 @default.
• W2078441609 hasConcept C178790620 @default.
• W2078441609 hasConcept C179104552 @default.
• W2078441609 hasConcept C184651966 @default.
• W2078441609 hasConcept C185592680 @default.
• W2078441609 hasConcept C192562407 @default.
• W2078441609 hasConcept C2776652806 @default.
• W2078441609 hasConcept C33790079 @default.
• W2078441609 hasConcept C504270822 @default.
• W2078441609 hasConcept C512968161 @default.
• W2078441609 hasConcept C66887884 @default.
• W2078441609 hasConcept C74575197 @default.
• W2078441609 hasConceptScore W2078441609C147789679 @default.
• W2078441609 hasConceptScore W2078441609C150394285 @default.
• W2078441609 hasConceptScore W2078441609C161790260 @default.
• W2078441609 hasConceptScore W2078441609C162711632 @default.
• W2078441609 hasConceptScore W2078441609C178790620 @default.
• W2078441609 hasConceptScore W2078441609C179104552 @default.
• W2078441609 hasConceptScore W2078441609C184651966 @default.
• W2078441609 hasConceptScore W2078441609C185592680 @default.
• W2078441609 hasConceptScore W2078441609C192562407 @default.
• W2078441609 hasConceptScore W2078441609C2776652806 @default.
• W2078441609 hasConceptScore W2078441609C33790079 @default.
• W2078441609 hasConceptScore W2078441609C504270822 @default.
• W2078441609 hasConceptScore W2078441609C512968161 @default.
• W2078441609 hasConceptScore W2078441609C66887884 @default.
• W2078441609 hasConceptScore W2078441609C74575197 @default.

• next