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- W2078444057 abstract "A technique is described for the study of collisional deexcitation of highly vibrationally excited polyatomic molecules by use of externally activated competitive unimolecular reaction systems. This method has some advantages and is illustrated by the decomposition of chemically activated hexyl-3 radicals in the presence of H 2 and CF 4 as heat bath molecules. The former removes ~1.2 kcal mole −1 per successful collision; while for the latter a value in excess of 4.6 kcal is found so that CF 4 behaves operationally like a strong collider." @default.
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- W2078444057 date "1968-01-15" @default.
- W2078444057 modified "2023-09-23" @default.
- W2078444057 title "Vibrational energy transfer. Collisional quenching of competitive unimolecular reactions" @default.
- W2078444057 doi "https://doi.org/10.1139/v68-055" @default.
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