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- W2078444513 abstract "Eight new R1CpTiCl2(OC(C6H4R2)Ph2) complexes were synthesized by the reaction of R1CpTiCl3 with Ph2(R2C6H4)COH (R2C6H4 = phenyl or o-methyl-phenyl) in the presence of Et3N in good yield and characterized by 1H NMR, elemental analysis, IR and mass spectrometry. A suitable single crystal of complex 2 (R1: CH3, R2: H) was obtained and the structure determined by X-ray diffraction. When activated by methylaluminoxane (MAO), all complexes were active for the polymerization of ethylene and styrene. The effect of variation in temperature, catalyst concentration and MAO/catalyst molar ratio was also studied. Complex 5 (R1: n-C4H9, R2: H) showed a moderate conversion (37.4%) for the polymerization of methyl methacrylate. Copyright © 2005 John Wiley & Sons, Ltd." @default.
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- W2078444513 date "2005-01-01" @default.
- W2078444513 modified "2023-10-10" @default.
- W2078444513 title "Titanium(IV) complexes containing mono-cyclopentadienyl and bulky trityloxy mixed ligands: synthesis and polymerization activity" @default.
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- W2078444513 doi "https://doi.org/10.1002/aoc.875" @default.
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