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- W2078455756 abstract "Successful crystallization and X-ray crystallographic analyses of the highly metastable (1∶1) complexes of bromine with benzene and toluene establish the unique (localized) structure B that differs in notable ways from the long-accepted (delocalized) structure A. Furthermore, we demonstrate the (highly structured) charge-transfer complexes [C6H6,Br2] and [CH3C6H5,Br2] to be the pre-reactive intermediates that are converted (via an overall Br+ transfer) to the Wheland intermediates in electrophilic aromatic bromination. The role of the dative ion pairs [C6H6˙+ Br2˙−] and [CH3C6H5˙+ Br2˙−] in the rate-limiting activation processes is underscored." @default.
- W2078455756 created "2016-06-24" @default.
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- W2078455756 date "2002-04-15" @default.
- W2078455756 modified "2023-10-16" @default.
- W2078455756 title "Molecular structures of the metastable charge-transfer complexes of benzene (and toluene) with bromine as the pre-reactive intermediates in electrophilic aromatic bromination" @default.
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- W2078455756 doi "https://doi.org/10.1039/b110169m" @default.
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