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- W2078463352 abstract "Diluted acids (typically 0.05 M HCl) are shown to be very effective media to promote the alkylation of phenols with activated alcohols under hydrothermal conditions (from 150 to 200 °C). These results are an elegant alternative to “usual” Friedel-Crafts alkylations avoiding the use of alkylchlorides as alkylating agents and the use of Lewis acidic promoters or concentrated acids but also shade some light on the processes occurring during the hydrothermal carbonisation (HTC) of biomass. Dans ce manuscrit nous montrons que les acides faiblement concentrés (concentration de l’ordre de 0,05 M) se trouvent être de très bons milieux pour réaliser l’alkylation de composés phénoliques par des alcools en conditions hydrothermales (entre 150 et 200 °C). Cette approche constitue non seulement une alternative élégante aux autres méthodes d’alkylation des phénols mais elle permet aussi de mieux comprendre les mécanismes à l’œuvre lors de la carbonisation hydrothermale de la biomasse (HTC)." @default.
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- W2078463352 date "2012-01-01" @default.
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- W2078463352 title "Hydrothermal alkylation of phenols with alcohols in diluted acids" @default.
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- W2078463352 doi "https://doi.org/10.1016/j.crci.2011.11.016" @default.
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