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- W2078472211 abstract "Abstract Treatment of N-tosyl aziridine with KPPh2 in THF produces Ph2PCH2CH2NTsK (Ts = p-CH3C6H4SO2). Reaction of Ph2PCH2CH2NTsK with [Rh2(μ2-Cl)2(NBD)2] (NBD = norbornadiene) and [Rh2(μ2-Cl)2(COD)2] (COD = 1,5-cyclooctadiene) produces [Rh(NBD)(Ph2PCH2CH2NTs)] and [Rh(COD)(Ph2PCH2CH2NTs)] (4), respectively. Reaction of Ph2PCH2CH2NTsK with [Ir2(μ2-Cl)2(COD)2] gives [Ir(COD)(Ph2PCH2CH2NTs)]. Complex 4 is catalytically active for polymerization of arylalkynes and for cyclotrimerization of HC CCOR (R = OEt, Me). The novel metallacycle [Rh(C(CO2Et) CHC(CO2Et) CH)(CH(CO2Et) CC CCO2Et)(Ph2PCH2CH2NHTs)2] was isolated from the reaction of 4 with ethyl propiolate. The metallacycle is catalytically active for cyclotrimerization of ethyl propiolate." @default.
- W2078472211 created "2016-06-24" @default.
- W2078472211 creator A5019015132 @default.
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- W2078472211 date "2006-04-01" @default.
- W2078472211 modified "2023-10-11" @default.
- W2078472211 title "Alkyne oligomerization mediated by rhodium complexes with a phosphinosulfonamido ligand and isolation and characterization of a rhodacyclopentadiene complex" @default.
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- W2078472211 doi "https://doi.org/10.1016/j.jorganchem.2006.01.004" @default.
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