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- W2078476003 abstract "The reaction of antimony (III) halides, SbX3, with Lewis bases has been studied calorimetrically in 1.2-dichloroethane solution. The O-donors, Ph3PO, Me2SO and pyridine-N-oxide, form 1:1 adducts mostly of high stability but with small enthalpies of formation. Phosphines also form 1:1 adducts, though PBu3 gives both SbCl3PBu3 and SbCl3(PBU3)2: diphosphines are unidentate but some of the complex diphosphine (SbCl3)2 is formed when SbCl3 is in excess. Aromatic amines form 1:1 adducts of moderate stability (100 < K < 2500 1 mole−1) with rather large enthalpies of formation, mostly about 100 kJ mole−1. Heterocyclic bases form very stable 1:1 adducts (K < 103 1 mole−1) with enthalpies of formation around 90 kJ mole−1; a second molecule of base can also be added with K2 < K1 and -ΔH2 < - ΔH1 - Enthalpies of formation of adducts with 2,2′-bipyridine and 1,10-phenanthroline are less than those of 1:1 adducts with pyridine. Aliphatic amines and 2,4,6-trimethylpyridine form adducts of the type SbX3B3 of very high stability with enthalpies of formation about 250 kJ mole−1. There is some evidence that in these adducts the base is coordinated to halogen rather than antimony." @default.
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- W2078476003 date "1978-12-01" @default.
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- W2078476003 title "Reaction of antimony(III) halides with Lewis bases" @default.
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- W2078476003 doi "https://doi.org/10.1016/0040-6031(78)85042-4" @default.
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