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- W2078478927 abstract "Abstract Hydrogen atom abstraction and cycloaddition–cycloreversion reactions between ionized vinylamine and neutral olefins were studied in a Fourier transform ion cyclotron resonance spectrometer. The efficiencies of both processes are appreciably less than unity. The trend in reaction efficiencies is consistent with the presence of a substantial intrinsic barrier but interpretation based on constraints inherent to the approach of the reactants cannot be discarded. The regioselectivity observed during the cycloaddition–cycloreversion reactions closely parallels the nucleophilic attack of an olefin by a free radical. The thermochemistry of these reactions and partial potential energy surfaces were examined with the help of experimental data and molecular orbital calculations (MP2/6–31G*//3–21G)." @default.
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- W2078478927 date "1993-03-01" @default.
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- W2078478927 title "Reactivity of vinylamine radical cation with neutral olefins: An example of ‘ionic’ free-radical chemistry in the gas phase" @default.
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- W2078478927 doi "https://doi.org/10.1002/oms.1210280321" @default.
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