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- W2078479216 abstract "The three-component condensation reaction of indoles with carbonyl compounds to yield bis(indolyl)methanes has been accomplished with a catalytic amount of iodine (2 mol%) in the presence of sodium dodecylsulfate (SDS) in aqueous solution above its critical micellar concentration (cmc). The surfactant-aided water-compatible Lewis acid catalyst has been found to be efficient for a wide range of carbonyl compounds including aromatic aldehydes bearing electron-releasing and electron-withdrawing groups, α,β-unsaturated aldehydes, heterocyclic aldehydes, cyclic and aromatic ketones with respect to yield, and reaction time. The protocol has been extended to Michael addition of indoles with α,β-unsaturated ketones exclusively yielding 3-substituted indolyl ketones in excellent yields." @default.
- W2078479216 created "2016-06-24" @default.
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- W2078479216 date "2012-03-01" @default.
- W2078479216 modified "2023-10-16" @default.
- W2078479216 title "Iodine in aqueous micellar environment: a mild effective ecofriendly catalytic system for expedient synthesis of bis(indolyl)methanes and 3-substituted indolyl ketones" @default.
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- W2078479216 doi "https://doi.org/10.1080/17518253.2011.581700" @default.
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