Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078484473> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2078484473 endingPage "84" @default.
- W2078484473 startingPage "75" @default.
- W2078484473 abstract "A methodology, which determines the operating conditions simultaneously optimising the chemical yield and considering the safety aspect, has been developed for a chemical reaction which is carried out batch-wise. To illustrate the methodology, the aromatic nitration of toluene by mixed acid has been chosen as a typical exothermic and non-selective reaction. This reaction takes place in a two-phase medium and, therefore, involves simultaneously chemical reaction and mass transfer phenomena. A kinetic model recently proposed for the slow and fast liquid–liquid reaction regimes was integrated to the mass balance. Nitration experiments were carried out in order to compare experimental composition profiles with simulated ones. Afterwards, an optimisation procedure has been used to maximise conversion, by manipulating the operating conditions subject to safety constraints. The p-nitrotoluene yield was chosen as the criterion to be maximised. Experimental validation for the optimisation procedure has been carried out. A monofluid heating–cooling system controlled by a predictive controller was used for the temperature control of the reactor. Simulation and experimental results are presented, discussed and compared." @default.
- W2078484473 created "2016-06-24" @default.
- W2078484473 creator A5027876818 @default.
- W2078484473 creator A5041201567 @default.
- W2078484473 creator A5053445272 @default.
- W2078484473 creator A5066003513 @default.
- W2078484473 date "2003-01-01" @default.
- W2078484473 modified "2023-09-30" @default.
- W2078484473 title "Modelling and constraint optimisation of an aromatic nitration in liquid–liquid medium" @default.
- W2078484473 cites W1963885199 @default.
- W2078484473 cites W1974222754 @default.
- W2078484473 cites W1977307800 @default.
- W2078484473 cites W2015921624 @default.
- W2078484473 cites W2747173866 @default.
- W2078484473 doi "https://doi.org/10.1016/s1385-8947(02)00139-0" @default.
- W2078484473 hasPublicationYear "2003" @default.
- W2078484473 type Work @default.
- W2078484473 sameAs 2078484473 @default.
- W2078484473 citedByCount "20" @default.
- W2078484473 countsByYear W20784844732012 @default.
- W2078484473 countsByYear W20784844732015 @default.
- W2078484473 countsByYear W20784844732017 @default.
- W2078484473 countsByYear W20784844732020 @default.
- W2078484473 countsByYear W20784844732021 @default.
- W2078484473 countsByYear W20784844732022 @default.
- W2078484473 countsByYear W20784844732023 @default.
- W2078484473 crossrefType "journal-article" @default.
- W2078484473 hasAuthorship W2078484473A5027876818 @default.
- W2078484473 hasAuthorship W2078484473A5041201567 @default.
- W2078484473 hasAuthorship W2078484473A5053445272 @default.
- W2078484473 hasAuthorship W2078484473A5066003513 @default.
- W2078484473 hasConcept C121332964 @default.
- W2078484473 hasConcept C127413603 @default.
- W2078484473 hasConcept C134121241 @default.
- W2078484473 hasConcept C161790260 @default.
- W2078484473 hasConcept C177801218 @default.
- W2078484473 hasConcept C178790620 @default.
- W2078484473 hasConcept C185592680 @default.
- W2078484473 hasConcept C21880701 @default.
- W2078484473 hasConcept C2775856698 @default.
- W2078484473 hasConcept C2778142098 @default.
- W2078484473 hasConcept C43617362 @default.
- W2078484473 hasConcept C45119746 @default.
- W2078484473 hasConcept C47502133 @default.
- W2078484473 hasConcept C51038369 @default.
- W2078484473 hasConcept C97355855 @default.
- W2078484473 hasConceptScore W2078484473C121332964 @default.
- W2078484473 hasConceptScore W2078484473C127413603 @default.
- W2078484473 hasConceptScore W2078484473C134121241 @default.
- W2078484473 hasConceptScore W2078484473C161790260 @default.
- W2078484473 hasConceptScore W2078484473C177801218 @default.
- W2078484473 hasConceptScore W2078484473C178790620 @default.
- W2078484473 hasConceptScore W2078484473C185592680 @default.
- W2078484473 hasConceptScore W2078484473C21880701 @default.
- W2078484473 hasConceptScore W2078484473C2775856698 @default.
- W2078484473 hasConceptScore W2078484473C2778142098 @default.
- W2078484473 hasConceptScore W2078484473C43617362 @default.
- W2078484473 hasConceptScore W2078484473C45119746 @default.
- W2078484473 hasConceptScore W2078484473C47502133 @default.
- W2078484473 hasConceptScore W2078484473C51038369 @default.
- W2078484473 hasConceptScore W2078484473C97355855 @default.
- W2078484473 hasIssue "1" @default.
- W2078484473 hasLocation W20784844731 @default.
- W2078484473 hasOpenAccess W2078484473 @default.
- W2078484473 hasPrimaryLocation W20784844731 @default.
- W2078484473 hasRelatedWork W2001454621 @default.
- W2078484473 hasRelatedWork W2013053196 @default.
- W2078484473 hasRelatedWork W2029363212 @default.
- W2078484473 hasRelatedWork W2078329040 @default.
- W2078484473 hasRelatedWork W2356075381 @default.
- W2078484473 hasRelatedWork W2364758788 @default.
- W2078484473 hasRelatedWork W2375790885 @default.
- W2078484473 hasRelatedWork W2380264547 @default.
- W2078484473 hasRelatedWork W3138280580 @default.
- W2078484473 hasRelatedWork W4311969550 @default.
- W2078484473 hasVolume "91" @default.
- W2078484473 isParatext "false" @default.
- W2078484473 isRetracted "false" @default.
- W2078484473 magId "2078484473" @default.
- W2078484473 workType "article" @default.