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• W2078485536 abstract "Abstract The structural phase transitions of the layer compound BaMnF4 were studied by high-resolution X-ray diffraction using synchrotron radiation. The intensities and profiles of two kinds of superlattice reflections having incommensurate reduced wave vectors q 1= (∼ ± 1/5,0,0) p and q 2 =(∼ ± 2/5,1/2,1/2)p, respectively, were measured as a function of temperature from 25 K to 280 K. These temperature dependencies show that incommensurate structural phase transitions of second order occur at 234 K and 244 K. These structural phase transitions are interpreted as successive condensations of a folding-screen-like incommensurate plane-distortion mode and a commensurate anti-ferro-distortive tilting mode of the MnF6 octahedra around the primitive a0 - and b0 -axes, when cooled down. It is also found that there is another structural phase transition at about 45 K related to a precursor structural distortion for the antiferromagnetic transition occurring at about 26 K." @default.
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• W2078485536 date "2001-05-01" @default.
• W2078485536 modified "2023-10-16" @default.
• W2078485536 title "Incommensurate cooperative tilting modes of MnF6octahedra relatedto the structural phasetransitions in BaMnF4" @default.
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• W2078485536 doi "https://doi.org/10.1080/01411590108224556" @default.
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