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- W2078486775 abstract "Treatment of [Ir(cod)(dippe)]PF6 (1) (dippe = 1,2 bis(diisopropylphosphino) ethane, PPri2(CH2)2PPri2) with molecular hydrogen at room temperature, in benzene and in the presence of 10 equivalents of NEt3, affords the binuclear polyhydride complex [Ir2(μ-H)3H2(dippe)2]PF6 (2) and not [IrH5(dippe)]. The complex [Ir2(μ-H)3H2(dippe)2]PF6 (2) is shown to be fluxional in solution, whereby the hydrides and the phosphorus ligands exchange rapidly at room temperature with respect to the NMR time scale." @default.
- W2078486775 created "2016-06-24" @default.
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- W2078486775 date "1989-01-01" @default.
- W2078486775 modified "2023-09-26" @default.
- W2078486775 title "Synthesis and spectroscopic characterization of a novel iridium polyhydride [Ir2(μ-H)3H2(dippe)2]PF6; dippe = 1,2 bis(diisopropylphosphino)ethane" @default.
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- W2078486775 doi "https://doi.org/10.1016/s0277-5387(00)86418-9" @default.
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