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- W2078492906 abstract "The synthesis of the high-nuclearity FeIII14 coordination cluster [Fe14(μ3-O)6(μ3-OH)4(μ-OH)3Cl11(dea)4(Hdea)3]Cl·H2O·27MeCN (1) is reported (in which deaH2 = diethanolamine). X-ray crystallographic analysis revealed that compound 1 crystallises in the cubic space group Im with Z = 24 and 8 independent Fe centres. Unusually for an FeIII coordination cluster, the FeIII centres in 1 adopt a range of 4, 5 and 6 coordinate geometries. Complex 1 presents a ferracalixarene topology which can be described in terms of a “half tennis ball” structure and binds a chloride anion guest via multiple hydrogen bonds. The curvature in the structure induced by this topology affects the overall spin structure. A ground spin state of S = 7 is proposed using a combination of magnetic susceptibility data and density functional theory (DFT) calculations." @default.
- W2078492906 created "2016-06-24" @default.
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- W2078492906 date "2013-01-01" @default.
- W2078492906 modified "2023-10-17" @default.
- W2078492906 title "Spins on a curved surface: an FeIII14 ferracalixarene" @default.
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- W2078492906 doi "https://doi.org/10.1039/c3dt50345c" @default.
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