FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078495167> ?p ?o ?g. }

• W2078495167 endingPage "1175" @default.
• W2078495167 startingPage "1167" @default.
• W2078495167 abstract "The mineralization of acidic aqueous solutions of the herbicide desmetryne has been studied by electrochemical advanced oxidation processes (EAOPs) such as anodic oxidation with electrogenerated H2O2 (AO-H2O2), electro-Fenton (EF) and photoelectro-Fenton (PEF) with UVA light. Electrolyses were conducted in an open and cylindrical cell with a boron-doped diamond (BDD) anode and an O2-diffusion cathode for H2O2 generation. The main oxidizing species are OH radicals formed at the BDD surface in all treatments and in the bulk from Fenton’s reaction between added Fe2+ and electrogenerated H2O2 in EF and PEF. A poor mineralization was attained using AO-H2O2 by the slow oxidation of persistent by-products with OH at the BDD surface. The synergistic action of OH in the bulk enhanced the degradation rate in EF, although almost total mineralization was only achieved in PEF due to the additional OH generation and photolysis of intermediates by UVA irradiation. The effect of current, pH and herbicide concentration on the mineralization degree and mineralization current efficiency of each EAOP was examined. Desmetryne decay always followed a pseudo first-order kinetics, being more rapidly destroyed in the sequence AO-H2O2 < EF < PEF. In all EAOPs, ammeline and cyanuric acid were identified as persistent heteroaromatic by-products and oxamic and formic acids were detected as generated carboxylic acids. The generation of cyanuric acid mainly by oxidation with OH at the BDD surface is the predominant path for desmetryne degradation. The initial nitrogen of desmetryne yielded NO3- ion in low proportion and NH4+ ion in much lesser extent, suggesting that its major part was lost as volatile N-derivatives." @default.
• W2078495167 created "2016-06-24" @default.
• W2078495167 creator A5007941314 @default.
• W2078495167 creator A5011929776 @default.
• W2078495167 creator A5020667160 @default.
• W2078495167 creator A5021701743 @default.
• W2078495167 date "2011-11-01" @default.
• W2078495167 modified "2023-09-26" @default.
• W2078495167 title "Mineralization of desmetryne by electrochemical advanced oxidation processes using a boron-doped diamond anode and an oxygen-diffusion cathode" @default.
• W2078495167 cites W1972291331 @default.
• W2078495167 cites W1975382711 @default.
• W2078495167 cites W1976306365 @default.
• W2078495167 cites W1981452053 @default.
• W2078495167 cites W1983047026 @default.
• W2078495167 cites W1984959236 @default.
• W2078495167 cites W1989682198 @default.
• W2078495167 cites W1995006498 @default.
• W2078495167 cites W1996836529 @default.
• W2078495167 cites W2000663251 @default.
• W2078495167 cites W2001700734 @default.
• W2078495167 cites W2004585088 @default.
• W2078495167 cites W2014808889 @default.
• W2078495167 cites W2015623086 @default.
• W2078495167 cites W2020517283 @default.
• W2078495167 cites W2031183982 @default.
• W2078495167 cites W2035833216 @default.
• W2078495167 cites W2036275772 @default.
• W2078495167 cites W2036917351 @default.
• W2078495167 cites W2038548953 @default.
• W2078495167 cites W2042657941 @default.
• W2078495167 cites W2044139626 @default.
• W2078495167 cites W2045535596 @default.
• W2078495167 cites W2047687948 @default.
• W2078495167 cites W2052406465 @default.
• W2078495167 cites W2065739020 @default.
• W2078495167 cites W2070975150 @default.
• W2078495167 cites W2084848986 @default.
• W2078495167 cites W2086952161 @default.
• W2078495167 cites W2093421844 @default.
• W2078495167 cites W2112238783 @default.
• W2078495167 cites W2143546017 @default.
• W2078495167 cites W2155061806 @default.
• W2078495167 cites W2160659516 @default.
• W2078495167 cites W2323605512 @default.
• W2078495167 cites W2395916495 @default.
• W2078495167 cites W2406993288 @default.
• W2078495167 doi "https://doi.org/10.1016/j.chemosphere.2011.09.008" @default.
• W2078495167 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21996652" @default.
• W2078495167 hasPublicationYear "2011" @default.
• W2078495167 type Work @default.
• W2078495167 sameAs 2078495167 @default.
• W2078495167 citedByCount "40" @default.
• W2078495167 countsByYear W20784951672012 @default.
• W2078495167 countsByYear W20784951672013 @default.
• W2078495167 countsByYear W20784951672014 @default.
• W2078495167 countsByYear W20784951672015 @default.
• W2078495167 countsByYear W20784951672016 @default.
• W2078495167 countsByYear W20784951672017 @default.
• W2078495167 countsByYear W20784951672018 @default.
• W2078495167 countsByYear W20784951672019 @default.
• W2078495167 countsByYear W20784951672020 @default.
• W2078495167 countsByYear W20784951672021 @default.
• W2078495167 countsByYear W20784951672022 @default.
• W2078495167 crossrefType "journal-article" @default.
• W2078495167 hasAuthorship W2078495167A5007941314 @default.
• W2078495167 hasAuthorship W2078495167A5011929776 @default.
• W2078495167 hasAuthorship W2078495167A5020667160 @default.
• W2078495167 hasAuthorship W2078495167A5021701743 @default.
• W2078495167 hasConcept C111696902 @default.
• W2078495167 hasConcept C139066938 @default.
• W2078495167 hasConcept C13965031 @default.
• W2078495167 hasConcept C145148216 @default.
• W2078495167 hasConcept C147789679 @default.
• W2078495167 hasConcept C17525397 @default.
• W2078495167 hasConcept C178790620 @default.
• W2078495167 hasConcept C179104552 @default.
• W2078495167 hasConcept C184651966 @default.
• W2078495167 hasConcept C185592680 @default.
• W2078495167 hasConcept C2775979504 @default.
• W2078495167 hasConcept C2777683982 @default.
• W2078495167 hasConcept C2778468930 @default.
• W2078495167 hasConcept C52859227 @default.
• W2078495167 hasConcept C537208039 @default.
• W2078495167 hasConcept C77176794 @default.
• W2078495167 hasConcept C89395315 @default.
• W2078495167 hasConceptScore W2078495167C111696902 @default.
• W2078495167 hasConceptScore W2078495167C139066938 @default.
• W2078495167 hasConceptScore W2078495167C13965031 @default.
• W2078495167 hasConceptScore W2078495167C145148216 @default.
• W2078495167 hasConceptScore W2078495167C147789679 @default.
• W2078495167 hasConceptScore W2078495167C17525397 @default.
• W2078495167 hasConceptScore W2078495167C178790620 @default.
• W2078495167 hasConceptScore W2078495167C179104552 @default.
• W2078495167 hasConceptScore W2078495167C184651966 @default.
• W2078495167 hasConceptScore W2078495167C185592680 @default.
• W2078495167 hasConceptScore W2078495167C2775979504 @default.
• W2078495167 hasConceptScore W2078495167C2777683982 @default.
• W2078495167 hasConceptScore W2078495167C2778468930 @default.

• next