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- W2078497642 abstract "A catalytic reductive coupling of aldimines was achieved by using a catalyst Cp2VCl2/PhMe2SiCl/Zn system. The influence of the catalyst, chlorosilane, co-reductant, solvent, and temperature on both the yield and diastereoselectivity of the coupling products was investigated in detail. As a result, the present Cp2VCl2-catalyzed reductive coupling of aldimines in the presence of PhMe2SiCl and zinc metal provided the corresponding 1,2-diamines in good yield with high meso selectivity (up to 92% meso), while the reductive coupling of aldehydes, ketones, and aldimines by the hitherto known catalytic methods leads to the preferential formation of dl isomers of the coupling products." @default.
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- W2078497642 date "2010-06-15" @default.
- W2078497642 modified "2023-09-26" @default.
- W2078497642 title "ChemInform Abstract: Cp2VCl2-Catalyzed meso-Selective Pinacol Coupling Reaction of Aldimines in the Presence of Chlorosilane and Zinc Metal." @default.
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- W2078497642 doi "https://doi.org/10.1002/chin.199924080" @default.
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