Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078505562> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2078505562 endingPage "6087" @default.
- W2078505562 startingPage "6081" @default.
- W2078505562 abstract "Exchange experiments utilizing Ru(bpy)2(4,4‘-(CO2H)2bpy)2+ and Os(bpy)2(4,4‘-(CO2H)2bpy)2+ (4,4‘-(CO2H)2bpy is 4,4‘-dicarboxy-2,2‘-bipyridine) provide evidence for a distribution of binding sites on ITO electrodes by electrochemical monitoring and on optically transparent, nanoparticle TiO2 films by optical monitoring. Using the Albery model of dispersed kinetics for the analysis of exchange, the results are consistent with dissociative loss from the surface with k1 = 0.1 s-1 for the dissociative step in CH3CN on ITO. Equilibrium binding data after exchange suggest that a site or distribution of sites is also present that undergoes exchange on a very slow time scale. Complete exchange takes place in EtOH, and the rate is greatly enhanced compared to that in CH3CN, suggesting that EtOH labilizes the surface to exchange. On TiO2 the time scale for exchange is far longer than that on ITO, and in CH3CN it scales with film thickness." @default.
- W2078505562 created "2016-06-24" @default.
- W2078505562 creator A5033772791 @default.
- W2078505562 creator A5089516413 @default.
- W2078505562 date "2003-06-27" @default.
- W2078505562 modified "2023-10-16" @default.
- W2078505562 title "Kinetics of Absorbed Chromophore Exchange on Metal Oxide Electrodes" @default.
- W2078505562 cites W1666246430 @default.
- W2078505562 cites W1966836042 @default.
- W2078505562 cites W1967133353 @default.
- W2078505562 cites W1971193815 @default.
- W2078505562 cites W1979814706 @default.
- W2078505562 cites W1998015708 @default.
- W2078505562 cites W2013010707 @default.
- W2078505562 cites W2019434195 @default.
- W2078505562 cites W2036268565 @default.
- W2078505562 cites W2048093472 @default.
- W2078505562 cites W2051261601 @default.
- W2078505562 cites W2057846441 @default.
- W2078505562 cites W2065557698 @default.
- W2078505562 cites W2066516787 @default.
- W2078505562 cites W2067520104 @default.
- W2078505562 cites W2080775153 @default.
- W2078505562 cites W2081225172 @default.
- W2078505562 cites W2108837335 @default.
- W2078505562 cites W4213245659 @default.
- W2078505562 cites W4241456496 @default.
- W2078505562 doi "https://doi.org/10.1021/la0268909" @default.
- W2078505562 hasPublicationYear "2003" @default.
- W2078505562 type Work @default.
- W2078505562 sameAs 2078505562 @default.
- W2078505562 citedByCount "6" @default.
- W2078505562 countsByYear W20785055622015 @default.
- W2078505562 countsByYear W20785055622017 @default.
- W2078505562 countsByYear W20785055622018 @default.
- W2078505562 countsByYear W20785055622019 @default.
- W2078505562 crossrefType "journal-article" @default.
- W2078505562 hasAuthorship W2078505562A5033772791 @default.
- W2078505562 hasAuthorship W2078505562A5089516413 @default.
- W2078505562 hasConcept C113196181 @default.
- W2078505562 hasConcept C121332964 @default.
- W2078505562 hasConcept C147789679 @default.
- W2078505562 hasConcept C148898269 @default.
- W2078505562 hasConcept C17525397 @default.
- W2078505562 hasConcept C178790620 @default.
- W2078505562 hasConcept C179104552 @default.
- W2078505562 hasConcept C185592680 @default.
- W2078505562 hasConcept C192468462 @default.
- W2078505562 hasConcept C2779851234 @default.
- W2078505562 hasConcept C52859227 @default.
- W2078505562 hasConcept C544153396 @default.
- W2078505562 hasConcept C62520636 @default.
- W2078505562 hasConcept C75473681 @default.
- W2078505562 hasConceptScore W2078505562C113196181 @default.
- W2078505562 hasConceptScore W2078505562C121332964 @default.
- W2078505562 hasConceptScore W2078505562C147789679 @default.
- W2078505562 hasConceptScore W2078505562C148898269 @default.
- W2078505562 hasConceptScore W2078505562C17525397 @default.
- W2078505562 hasConceptScore W2078505562C178790620 @default.
- W2078505562 hasConceptScore W2078505562C179104552 @default.
- W2078505562 hasConceptScore W2078505562C185592680 @default.
- W2078505562 hasConceptScore W2078505562C192468462 @default.
- W2078505562 hasConceptScore W2078505562C2779851234 @default.
- W2078505562 hasConceptScore W2078505562C52859227 @default.
- W2078505562 hasConceptScore W2078505562C544153396 @default.
- W2078505562 hasConceptScore W2078505562C62520636 @default.
- W2078505562 hasConceptScore W2078505562C75473681 @default.
- W2078505562 hasIssue "15" @default.
- W2078505562 hasLocation W20785055621 @default.
- W2078505562 hasOpenAccess W2078505562 @default.
- W2078505562 hasPrimaryLocation W20785055621 @default.
- W2078505562 hasRelatedWork W1570483242 @default.
- W2078505562 hasRelatedWork W1969933858 @default.
- W2078505562 hasRelatedWork W1979361567 @default.
- W2078505562 hasRelatedWork W1982215539 @default.
- W2078505562 hasRelatedWork W2000920557 @default.
- W2078505562 hasRelatedWork W2019028085 @default.
- W2078505562 hasRelatedWork W2116035760 @default.
- W2078505562 hasRelatedWork W2188427199 @default.
- W2078505562 hasRelatedWork W2442248805 @default.
- W2078505562 hasRelatedWork W2608269804 @default.
- W2078505562 hasVolume "19" @default.
- W2078505562 isParatext "false" @default.
- W2078505562 isRetracted "false" @default.
- W2078505562 magId "2078505562" @default.
- W2078505562 workType "article" @default.