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- W2078506768 abstract "Benzenechromium tricarbonyl C6H6Cr(CO)3 and thiophenechromium tricarbonyl C4H4SCr(CO)3 are isomorphous at room temperature. We have measured, in the range 77–295°K, the variations of specific heat and of the tensor of thermal expansion for these two molecular compounds. The first one exhibits quite normal behavior; on the other hand, the second one exhibits a first order phase transition, monoclinic ⇆ triclinic at T = 185°K, associated with an order-disorder phase transition. Structural evolution of thiophene-chromium tricarbonyl, during phase transition, has been explained from the variation of its tensor of thermal expansion." @default.
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- W2078506768 date "1978-07-01" @default.
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- W2078506768 title "Evolution des tenseurs de dilatation thermique en fonction de la temperature. II. Etude calorimetrique et cristallographique de la transition de phase ordre-desordre du thiophene chrome tricarbonyle C4H4SCr(CO)3" @default.
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- W2078506768 doi "https://doi.org/10.1016/0022-4596(78)90106-8" @default.
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