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- W2078507060 abstract "In several practical systems, metals may be exposed at elevated temperatures to environements containing O2 and S2. It commonly happens that Cr2O3-forming alloys which oxidize protectively for considerable times can be identified; however, there is a risk that, at times which are short in relation to the required component lifetime but long in comparison with test exposures, the corrosion rate may be accelerated. This is called breakaway corrosion, and the object of this study is to investigate the mechanism of the breakaway so that the possibility of its happening can be estimated from short-term tests. It is suggested that breakaway involves the development of a “critical microstructure” characterized by considerable intrusions of relatively coarse Cr2O3 fingers into he metal substrate. It is shown that these intrusions involve the progressive oxidation of a CrS “leader”. This also causes the oxide fingers to be porous, allowing gaseous species easy access to the reaction front." @default.
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- W2078507060 date "1987-03-01" @default.
- W2078507060 modified "2023-10-09" @default.
- W2078507060 title "The breakaway corrosion of FeCr alloys in atmospheres containing sulfur and oxygen" @default.
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- W2078507060 doi "https://doi.org/10.1016/0025-5416(87)90384-3" @default.
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