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- W2078509410 abstract "Perfluoroalkenes are obtained from perfluoroalkanes by photoinduced electron transfer from an organometallic photosensitizer, decamethylferrocene, in the polar solvent thf. In the presence of Zn, the reaction becomes catalytic in ferrocene because the decamethylferricinium product of the photolysis is reduced to the starting decamethylferrocene. Tertiary C−F bonds are the most reactive, and for example, perfluoro-1-methylcyclohexene is obtained from perfluoromethylcyclohexane with up to 110 turnovers and up to 12% conversion." @default.
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- W2078509410 date "1998-03-20" @default.
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- W2078509410 title "Catalytic Photodefluorination of Perfluoroalkanes to Perfluoroalkenes with a Ferrocene Photosensitizer" @default.
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- W2078509410 doi "https://doi.org/10.1021/om970871q" @default.
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