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- W2078512061 abstract "The Raman bandwidths and the frequency shifts of the ν12(A1) mode and the IR ν3(OH) stretching mode of phenol and phenol-OD have been measured as a function of concentration in benzonitrile and benzene solutions. Opposite isotope effects of deuterium substitution in the hydroxyl group of phenol on the bandwidths of the ν12 and the ν3(OH) modes have been found. The experimental bandwidths are discussed in terms of available theoretical models for dephasing and other mechanisms of broadening. The isolated binary collision dephasing model of Fischer-Laubereau, the Knapp-Fischer concentration-fluctuation model and the Robertson-Yarwood model have been tested. It has been stated that the purely repulsive potential is responsible for vibrational dephasing of the ν12 mode of phenol in benzene while the concentration-fluctuation model reproduces the experimental data for that mode in benzonitrile. The coupling between the ν3(OH) and ν2(OH…N) modes is the dominant mechanism for broadening of the ν3(OH) mode of phenol in benzonitrile." @default.
- W2078512061 created "2016-06-24" @default.
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- W2078512061 date "1985-04-01" @default.
- W2078512061 modified "2023-10-18" @default.
- W2078512061 title "Vibrational relaxation of phenol in benzonitrile and benzene solutions" @default.
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- W2078512061 doi "https://doi.org/10.1016/0301-0104(85)80062-8" @default.
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